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Integration of Fundamental Polymer Science and Technology—2 by P. Pino (auth.), P. J. Lemstra, L. A. Kleintjens (eds.)

By P. Pino (auth.), P. J. Lemstra, L. A. Kleintjens (eds.)

Polymer technology has matured right into a totally accredited department of fabrics technological know-how. which means it may be defined as a 'chain of data' (Manfred Gordon), the beads of the chain representing the entire themes that experience to be studied extensive if the connection among the constitution of the molecules synthesized and the end-use homes of the cloth they represent is to be understood. The time period chain shows the connectivity of the beads, i.e. the multidisciplinary technique required to accomplish the purpose, wisdom, right here outlined as quantitative realizing of the connection pointed out above in all its elements. a number of meetings are being held at which the disciplinar beads themselves are mentioned intimately, and new effects inside of their framework are awarded. during this recognize, the TUPAC Microsymposia in Prague have made themselves imperative, to say one profitable instance. The bi­ annual TUPAC Symposia on Macromolecules, nevertheless, offer interdisciplinary assembly areas, that have the virtue and the drawback of a big attendance. Smaller-size meetings of an analogous nature can frequently be stumbled on on a countrywide point. The organizers of the younger, yet already well-appreciated, Rolduc conferences at the interaction among primary technology and expertise within the polymer box struck a fascinating chord' after they discovered that focussing at the simple technological know-how in the back of technological difficulties might serve the aim of focus on perception alongside the chain of data and keep away from the give up to too huge a dimension for the assembly to truly be a meeting.

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So • SO SO 100 NP( in mol % (NPC)n-X-(ECL)m Figure 4. Thermal properties of blockcopolymers poly(l)(£-caprolactone) with tapered sequence X. 36 With increasing ~-caprolactone content the glass transition temperature decreases monotonically from 25°C to -65°C while the melting temperature shows a pronounced minimum of a composition of 70% NPC/30% ECL. Thus cyclic carbonates offer new ways to the formation of new products with a broad variety of properties. ACKNOWLEDGEMENT This project is sponsored by the Bundesministerium fur Forschung und Technologie and by Bayer AG.

Similar problems are encountered when adopting very high molecular mass polymers, often untractable being thermodegraded before softening. Post-cross linking of moulded parts, moreover, is a slow or incomplete process, which leads to dishomogeneous shrinkages and deformations. In principle, the RIM technology seems suitable to solve many of the above problems, provided that some fundamental requirements are satisfied, such as the absence of any adverse effect of the additive on the polymerization kinetics.

1986, 6, 1. D. M. Hedrick, Proc. 3rd Int. Conference on Reactive Processing of Polymers, Bischenberg 1984, pp. 137-148. M. V. I. B. V. USSR 1974, 16, 1452. Ya. G. N. S. A. USSR 1980, 22, 1097. 30 ANIONIC RING-OPENING POLYMERIZATION OF CARBONATES AND FORMATION OF BLOCKCOPOLYMERS Helmut Keul and Hartwig Hocker Lehrstuhl fur Textilchemie und Makromolekulare Chemie der RWTH Aachen Veltmanplatz 8, D-S100 Aachen West-Germany ABSTRACT Cyclic carbonates are accessible by reaction of diols with carbonic acid esters.

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