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Advances in Biomimetics by Anne George

By Anne George

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4 μm) were obtained. From Fig. 16a-c and Fig. 15b, one can clearly see the morphological change process of BaCrO4 with increasing time. The degree of split and the size of X-shaped structures increased with increasing time. The growth mechanism of BaCrO4 may follow the well-known Ostwald ripening process, in which the larger particles grow at the expense of the smaller ones (Sugimoto, 1987). Fig. 17. SEM micrographs of BaCrO4 crystals prepared using different P123 concentration. 8 g L-1. The insets of (a) and (b) show the individual BaCrO4 crystals.

27, 367-79. ; Miyamoto, T. & Nakamura, T. (2003). Bonelike apatite formation on ethylene-vinyl alcohol copolymer modified with silane coupling agent and calcium silicate solutions. Biomaterials 24, 1729-35. Owusu, G. & Litz, J. E. (2000). Hydrometallurgy 57, 23. ; Kornowski, A. & Weller, H. (2002). Angew. Chem. Int. Ed. 41, 1188-91. Penn, R. L. & Banfield, J. F. (1999). Geochimica et Cosmochimica Acta 63,1549-57. Qu, L. ; Dai, L. ; Xia, Z. H. & Wang, Z. L. (2008). Carbon Nanotube Arrays with Strong Shear Binding-On and Easy Normal Lifting-Off.

Reproduced with permission from Mater. Res. , 2009, 44, 288. Copyright 2009 Elsevier. 36 Advances in Biomimetics growth of the crystals, and influenced the crystal morphology. Due to the electrostatic interaction with Ba2+ ions, the negatively charged of polymer polar groups acted as active sites for the nucleation of BaCrO4. Yu et al. (2003) reported that some faces of the BaCrO4 crystal could adsorb negatively charged groups such as –PO3H2, –COOH of polymer by electrostatic attraction and block these faces from further growth.

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